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[C 21 H 28 N 4 S 2 ], monoclinic,  P 2 1 / c  (no. 14),  a  = 16.1880(2) Å,  b  = 6.8168(1) Å,  c  = 19.7605(2) Å,  β  = 106.412(1)°,  V  = 2091.73(5) Å 3 ,  Z  = 4,  R  gt ( F ) = 0.0281,  wR  ref ( F  2 ) = 0.0740,  T  = 100(2) K.

Crystal structure of 4-phenylpiperazin-1-ium (4-phenylpiperazin-1-yl)carbothioylsulfanide, [C 10 H 15 N 2 ][C 11 H 13 N 2 S 2 ]