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Reactions of organosilicon compounds catalyzed by nucleophiles are under extensive study more than twenty five years. In this field two excellent reviews are published [1,2]. A monograph dedicated to hypervalent organosilicon compounds was also published recently [3J. There are also two reviews on fluoride mediated reactions of fluorinated silanes [4], Fluoride ion as activator of silicon bonds is widely described in these works. The present work was carried out in continuation of the review published by Corriu et.al. in 1993 [2], Our aim is to describe modern methodologies in the synthesis of different classes of compounds (for example, alkenes, alkynes, and alcohols) mediated by silanes activated by fluoride ion. The influence of different sources of fluoride ions (Bu4NF, CsF, tris(dimethylamino)sulfur (trimethylsilyl)difluoride (TASF), tetrabutylammonium triphenyldifluorosilicate (TBAT) on the chemical process will be discussed. The fluoride ion mediated reactions of organosilicon compounds containing Si —X bonds (X = H, C, Si,Ge, Sn, N, O) and their use in organic synthesis published from January 1994 to December 2000 are reviewed.

RECENT ADVANCES IN FLUORIDE ION ACTIVATION OF SILICON BONDS IN ORGANIC SYNTHESIS