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S Y N T H E S I S A N D P H Y S I C O C H E M I C A L I N V E S T I G A T I O N S O N 16 A N D 18 M E M B E R E D [N4] M A C R O C Y C L E S M O D I F I E D W I T H A P P R O P R I A T E C A R B O N Y L F U N C T I O N S A C L O S E R M I M I C T O A S Y N T H E T I C C Y C L I C T E T R A P E P T I D E ; I S O L A T I O N OF S T A B L E E N C A P S U L A T E D D E R I V A T I V E S W I T H Z n ( I I ) , C d ( I I ) A N D H g ( I I ) I O N S

main group metal chemistry

SYNTHESIS AND PHYSICO-CHEMICAL INVESTIGATIONS ON 16 AND 18 MEMBERED [N4] MACROCYCLES MODIFIED WITH APPROPRIATE CARBONYL FUNCTIONS - A CLOSER MIMIC TO A SYNTHETIC CYCLIC TETRAPEPTIDE; ISOLATION OF STABLE ENCAPSULATED DERIVATIVES WITH Zn(II),Cd(II) AND Hg(II) IONS