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The crystal and molecular structures of [Me₃SN(TA)] and [Et₃Sn(TA)], where TA is 3-(2-thiophenyl)-2-propenoate, are reported. The structures are polymeric owing to the presence of bidentate bridging carboxylate ligands; no evidence was found for Sn to S interactions. The Sn atom geometries are distorted trigonal bipyramidal with the organo substituents occupying equatorial positions. The structures found for the title compounds conform to the trans-R₃SnO₂ motif.M. Danish, S. Ali, Μ. Mazhar, A. Badshah, T. Masood, E.R T. Tiekin

CRYSTAL AND MOLECULAR STRUCTURES OF TWO POLYMERIC TRIORGANOTIN 2-(2-THIOPHENYL)ETHYLENE-1 -CARBOXYLATE DERIVATIVES