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The reaction between CdCl 2  and PPh 2 {C 6 H 4  [CH 2 N(CH 2 CH 2 ) 2 O]-2} ( 1 ) in a 1:1 molar ratio resulted in the cadmium(II) complex CdCl 2 [PPh 2 {C 6 H 4 [CH 2 N(CH 2 CH 2 ) 2 O]-2}] ( 2 ). The complex  2  was characterized in solution by NMR spectroscopy ( 1 H,  13 C, and  31 P). Single-crystal X-ray diffraction studies revealed no intramolecular N→P interaction in  1 . The phosphane ligand behaves as a  P,N  chelating moiety in the cadmium complex  2 , thus resulting in a species containing distorted tetrahedral environments around cadmium and phosphorus. Short intermolecular interactions CH‧‧‧π aryl and CH‧‧‧O in  1  and CH‧‧‧π aryl and CH‧‧‧Cl in  2  resulted in supramolecular networks.

Coordination behavior of PPh 2 {C 6 H 4 [CH 2 N(CH 2 CH 2 ) 2 O]-2}: Case study CdCl 2 [PPh 2 {C 6 H 4 [CH 2 N(CH 2 CH 2 ) 2 O]-2}]