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The lead(II) chloride [{N^N iPr }PbCl] ( 1 ), where {N^N} −  is a bulky, monoanionic, bidentate iminoanilide ligand, was synthesised by salt metathesis between [{N^N iPr }Li] and PbCl 2 . The complex was characterised by X-ray diffraction crystallography and  207 Pb nuclear magnetic resonance (NMR) spectroscopy. It exists in the molecular solid state as a monometallic three-coordinate species, with two independent, similar but not identical molecules per asymmetric unit. The differences between the first coordination sphere of  1  and that of Fulton’s structurally related β-diketiminato complex [{N^N iPr }PbCl] are illustrated. The synthesis of  1  offers a convenient handle in the still underdeveloped organometallic and inorganic chemistry of lead(II), as exemplified by the synthesis of the alkyl complex [{N^N iPr }PbCH(CH 3 ) 2 ] ( 3 ). The iodo complex [{N^N iPr }PbI] ( 2 ) was also synthesised, but, unlike  1 , it showed limited stability in solution.

Heteroleptic lead(II)-halide complexes supported by a bulky iminoanilide ligand