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The structures of the Group 1 metal aminoalkoxides Li[OCH(CH 2 CNMe 2 ) 2 ] ( 1 ) and K[OCH(CH 2 CNMe 2 ) 2 ]∙HOCH(CH 2 CNMe 2 ) 2  ( 2 ) have been determined.  1  is a hexa­meric drum in which two Li 3 O 3  rings are joined co-facially, whereas  2  is tetrameric and adopts a K 4 O 4  ladder structure, novel for homoleptic potassium alkoxides.

Lithium and potassium aminoalkoxides