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On the basis of in-situ observations of the α/γ phase transformation in an iron-4.2 at.% Cr alloy, it was found that triple junctions with more random boundaries can be preferential sites for nucleation and that a two-stage migration of α/γ interphase boundaries can occur with highly different velocities, i. e. of 0.23 ~ 0.43 μm/sec for the α/γ two phase temperature region and 2.6 ~ 44 μm/sec for the c single phase region. The origin of the observed high migration velocities of α/c interphase boundaries and the generalized K-S orientation relationship between a new phase and the matrix are discussed on the basis of a possible role of {111} γ //{110} α  plane matching interphase boundaries in the α/γ phase transformation.

A mechanism of plane matching boundary-assisted α/γ phase transformation in Fe–Cr alloy based on in-situ observations