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This study reports on the first assessment of the treatment of sediment contaminated by organotin compounds using homogenous and heterogeneous photocatalysis. Photo-Fenton and photocatalysis of low level (µg/L) organotins in water were carried out. A quasi-complete degradation of tributyltin (TBT) in water (99.8%) was reached after 30 and 7 min for photocatalytic and photo-Fenton treatment, respectively. For the first time decontamination of highly polluted marine sediments by photo-oxidation proves that the use of UV and the production of hydroxyl radicals are an efficient way to treat organotins adsorbed onto marine sediment despite the complexity of the matrix.

Photo-oxidation of Tributyltin, Dibutyltin and Monobutyltin in Water and Marine Sediments