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Herein, we report the supramolecular complexes of cyclohexanocucurbit[6]uril (CyH 6 Q[6]) with Cu(ClO 4 ) 2 , Zn(ClO 4 ) 2 , and Mg(ClO 4 ) 2  in formic acid solution. The crystal structure was determined using single crystal X-ray diffraction. The analysis results showed that CyH 6 Q [6] formed a one-dimensional supramolecular chain with Cu(ClO 4 ) 2  and formed a supramolecular assembly with a mixture ratio of 2:3 with Zn(ClO 4 ) 2  and Mg(ClO 4 ) 2 . In this system,ClO4−{\text{ClO}}_{4}^{-}induced CyH 6 Q[6] and metal ions to form supramolecular complexes through ion–dipole interactions.

A study on the coordination of cyclohexanocucurbit[6]uril with copper, zinc, and magnesium ions