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Reactions of the organoplatinum complex [Pt(cod)(neoSi)Cl] (neoSi = (trimethylsilylmethyl) with the Ag(I) salts of oxo or fluoride containing anions A –  = NO 3  – , ClO 4  – , OTf  –  (trifluoromethanesulfonate) and SbF 6  –  lead to the desired abstraction of the chlorido ligand and precipitation of AgCl. However, further reaction of the resulting Pt complexes [Pt(cod)(neoSi) (solvent)] +  with diverse N-heterocyclic ligands L such as pyridines, caffeine, and guanine did not yield the targeted complexes [Pt(cod)(neoSi)(L)](A) in most of the cases, but to extensive decomposition yielding [Pt(cod)(Me) (solvent)] + , thus transforming the neoSi into a methyl ligand. A detailed study on the reaction with SbF 6  –  combining DFT calculations with NMR and MS revealed that Pt catalysed decomposition of SbF 6  ‒  and fluorination of the neoSi silicon atom leading to FSiMe 3 . When reacting the parent complex with Ag(BPh 4 ), the arylated derivative [Pt(cod)(neoSi)(Ph)] was obtained and characterised by multinuclear NMR, MS and single crystal XRD.

Reactions of the organoplatinum complex [Pt(cod) (neoSi)Cl] (neoSi = trimethylsilylmethyl) with the non-coordinating anions SbF 6 – and BPh 4 –