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We are engaged in a research program of experimental data on thermodynamic and transport properties of binary mixtures [1-5] in lately suggested correlation equations. Generally, the mixtures have non-ideal characters and show specific behaviour for which the interpretation of the nonideality is an interesting topic, especially with new concepts like Herráez exponent, friccohesity, Belda coefficients and reduced Redlich-Kister excess properties [1-43]. Theory of solutions is still far from sufficient to well treat non-idealities for liquid solution, in terms of properties of the constituent molecules [28-34]. The knowledge of the principal factors engaged in the non-ideality of fluid mixtures is important for a better understanding of excess viscosities and volumes and its derived functions. Regarding the practical importance of amide-alcohol solutions, N,N-dimethylformamide (DMF), in a certain manner is associated through of dipole-dipole interactions. Substantial structural effects are missing due to the lack of hydrogen bonding. Thus it acts as a protophilic aprotic solvent of large dipole moment (μ = 3.80 D) of molecules with a fairly high dielectric constant (ε = 36.71) at 298.15 K [1-5]. An ethanol molecule can interact with a N,N-dimethylA Novel Approach of Partial Derivatives to Estimate the Normal Boiling Temperature via Viscosity Arrhenius Behaviour in N,N-Dimethylformamide + Ethanol Fluid Systems

asian journal of chemistry/asian journal of chemistry

A Novel Approach of Partial Derivatives to Estimate the Normal Boiling Temperature via Viscosity Arrhenius Behaviour in N,N-Dimethylformamide + Ethanol Fluid Systems