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Polycyclotrimerization is put forward as a new route to the synthesis of polymers of various structures containing carbo-or hetero-cyclic rings in the chain. Examples are described to indicate typical results. The wide possibilities in terms of selecting initial monomers thus provide a means of preparing a variety of polymeric structures. Since investigations in this field have barely begun, the potential of the method is yet to be determined. Nevertheless, we can expect that further studies will reveal considerable new synthetic possibilities for polycyclotrimerization which will contribute further to the chemistry of synthetic polymers.

Polycyclotrimerization as a general route to polymers with rings in the chains