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A new route to an alkoxohexavanadate species leads to the isolation of a bowl-type dodecavanadate without a guest molecule in the cavity. The 1D tetravanadate, [V 4 O 11 ] 2- , is a good precursor for the alkoxohexavanadate, [V 6 O 13 (OCH 3 ) 6 ] 2- , which is then utilized for the [V6 + V6] coupling reaction to form the dodecavanadate, [V 12 O 42 ] 4- , with a capped dichloromethane molecule at the cavity entrance. We also obtained structural information on a newly discovered octadecavanadate,  [V 18 O 46 (NO 3 )] 5- ,in both the solid and solution states through extended X-ray absorption fine structure (EXAFS) studies. The existence of a chiral inorganic species in acetonitrile with double-stranded V8 chains was confirmed through EXAFS oscillations.

Synthesis of a bowl-type dodecavanadate by the coupling reaction of alkoxohexavanadate and discovery of a chiral octadecavanadate