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Magnetic and speci c heat data of the TmRhX (X = Ga, Ge) compounds are reported. These compounds crystallize in an orthorhombic crystal structure of the TiNiSi-type (space group Pnma). Magnetic data indicate that the compounds are antiferromagnets with the Neel temperature TN equal to 3.9 K for TmRhGa and 6.0 K for TmRhGe. Magnetic susceptibility of TmRhGe has an additional peak at Tt = 10.6 K. In TmRhGe temperature dependence of χ′′(T ), the positions of both the peaks at TN and Tt change with frequency indicating a relaxation process. These data suggest that with the decreasing temperature, rst a cluster glass state and next the long-range aniferromagnetic order exists.

Magnetism and Specific Heat of TmRhX (X = Ga, Ge) Compounds