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The crystal of Ce5Ni2Si3 was prepared by the Czochralski method. The X-ray photoemission spectroscopy was measured for the valence band and the core levels. Based on the Ce(3d) doublet and its satellites a small value of the hybridization parameter of the f-states with the conduction electrons Delta = 4 meV and the f-occupancy n(f) close to 1 were found. X-ray photoemission spectroscopy shows that the region between 0 and 3 eV is predominated by the Ni(3d) and Ce(4f) peaks. Some features of the multiplet structure of the Ce(4f) states are also visible close to the Fermi level.

Valence Band and Core Levels of Ce5Ni2Si3Crystal Studied by X-ray Photoemission Spectroscopy

Valence Band and Core Levels of Ce₅Ni₂Si₃Crystal Studied by X-ray Photoemission Spectroscopy