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We report valence states of ions in La0.7Ce0.3MnO3 thin films grown by a reactive dc magnetron sputtering, The measurements were performed by means of high-energy X-ray photoelectron spectroscopy using synchrotron radiation. It was found that Ce ion in the compound is either in tetravalent or trivalent chemical state, manganese is in divalent, trivalent and tetravalent states, while La ion existing in oxide and hydroxide chemical species is in trivalent state.

Valence States of Metal Ions in La0.7Ce0.3MnO3Thin Films

Valence States of Metal Ions in La_0.7Ce_0.3MnO₃Thin Films