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Polarization dependence of resonant anomalous surface x-ray scattering(RASXS) was studied for interfaces buried in electrolytes or in high-pressuregas. We demonstrate that RASXS exhibits strong polarization dependence when thesurface is only slightly modified by adsorption of light elements such ascarbon monoxide on platinum surfaces. s- and p-polarization RASXS data weresimulated with the latest version of ab initio multiple scattering calculations(FEFF8.2). Elementary considerations are additionally presented for the originof the polarization dependence in RASXS.Comment: 15 pages. Submitted to Phys. Rev. Let

Polarization-dependent resonant anomalous surface X-ray scattering of CO/Pt(111)