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The reaction of pharmacological active protic ionic liquid tris-(2-hydroxyethyl)ammonium 4-chlorophenylsulfanylacetate H + N(CH 2 CH 2 OH) 3  ∙ ( - OOCCH 2 SC 6 H 4 Cl-4) ( 1 ) with zinc or nickel chloride in a ratio of 2:1 affords stable at room temperature powder-like adducts [H + N(CH 2 CH 2 OH) 3 ] 2  ∙ [M(OOCCH 2 SC 6 H 4 Cl-4) 2 Cl 2 ] 2- , M = Zn ( 2 ), Ni ( 3 ). By recrystallization from aqueous alcohol compound  2  unexpectedly gives Zn(OOCCH 2 SC 6 H 4 Cl-4) 2  ∙ 2H 2 O ( 4 ). Unlike  2 , compound  3  gives crystals [N(CH 2 CH 2 OH) 3 ] 2 Ni 2+  · [ - OOCCH 2 SC 6 H 4 Cl-4] 2  ( 5 ), which have a structure of metallated ionic liquid. The structure of  5  has been proved by X-ray diffraction analysis. It is the first example of the conversion of a protic ionic liquid into potentially biological active metallated ionic liquid ( 1  →  3  →  5 ).

chemistry central journal

Reaction of pharmacological active tris-(2-hydroxyethyl)ammonium 4-chlorophenylsulfanylacetate with ZnCl2 or NiCl2: first conversion of a protic ionic liquid into metallated ionic liquid