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We fabricate and characterize carbon-fiber tips for their use in combinedscanning tunneling and force microscopy based on piezoelectric quartz tuningfork force sensors. An electrochemical fabrication procedure to etch the tipsis used to yield reproducible sub-100-nm apex. We also study electron transportthrough single-molecule junctions formed by a single octanethiol moleculebonded by the thiol anchoring group to a gold electrode and linked to a carbontip by the methyl group. We observe the presence of conductance plateaus duringthe stretching of the molecular bridge, which is the signature of the formationof a molecular junction.

Carbon-fiber tips for scanning probe microscopes and molecular electronics experiments