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In addition to clean and renewable energy generation, the subsequent storage and deliver y is likewise a critical facet to achieving long-term sustainable energy practices. The principal means for storing energy generated off-peak for later on-peak usage currently leaves a void between overall storage capability and power delivery. As a promising technological cand idate for efficient and reversible energy storage, pseudocapacitors are a subtechnology of electrochem ical capacitors (so-called supercapacitors or ultra capacitors) that utilize fast and reversible Faradaic redox reactions. Although manganese oxides (MnOX) possess a theoretical capacitance of 1233 F/g based on one-electron charge-transfer reactions between Mn and Mn they have systematically exhibited much lower specific capacitances (~100 F/g). Intensive research activities have been reported to increase the capacitance of MnO X materials, including the design nanostructured materials to shorten diffusion distance of ions and electrons or the incorporation with other conductive materials (e .g., active carbon, carbon nanotube, graphene, or conductive polymer) to improve the electrical conductivity and stability of MnO X.

Pseudocapacitive Mn3O4 octahedral Nanoparticles: Synthesis, Characterizations and Study of Charge-Transfer Using in Situ XANES and XRD