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We evaluate all the electron-phonon couplings derived from the one-bodyelectronic interactions, in both the adiabatic and extreme non-adiabatic limit,for a dimer with a non-degenerate orbital built from atomic wave functions ofGaussian shape. We find largely different values of the coupling parameters inthe two cases, as well as different expressions of the corresponding terms inthe Hamiltonian.Comment: 5 postscript figure

MODEL CALCULATION OF ELECTRON–PHONON COUPLINGS IN A DIMER WITH A NON-DEGENERATE ORBITAL