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I discuss our knowledge of the scalar sector of QCD and how it impacts thedetermination of the CKM angle \alpha from the isospin analysis of B\to \rho\pidecay.Comment: invited talk at International Workshop on Heavy Quarks and Leptons,  Vietri sul Mare, Salerno, Italy, 27 May - 1 Jun 200

Chiral dynamics and $B\to 3\pi$ decay