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In this paper, for the first time we demonstrate zero-power volatile-organic-chemical (VOC) detectors based on micromechanical switches suitable for plant health monitoring. Differently from state-of-the-art active chemical sensors, the device presented here exploits a completely passive, chemically-sensitive switch based on a bimaterial micro-cantilever and a passive switch-based readout mechanism to detect VOCs exceeding a pre-determined concentration released by unhealthy plants. When exposed to target VOCs, the polymer/metal bimaterial beam bends downward and trigger the switch due to the stress induced from the absorption of chemicals in the polymer layer. Here we show experimental demonstrations of detecting toluene, hexenol (cis-3-Hexen-1-ol, a chemical released from plants under attack by pests) and ethanol, respectively, with our fabricated prototypes. The demonstrated high sensitivity to ethanol (~8 nm/ppm) and hexenol (~3.3 nm/ppm) was achieved by the optimization of device geometries showing a great promise of the proposed technology to ultimately achieve 10s ppm detection limit (with a sub-micron contact gap and voltage bias) which is required for the device operation in close proximity to a plant in an open environment. [2020-0190].

Micromechanical Switch-Based Zero-Power Chemical Detectors for Plant Health Monitoring