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The crystal structure of oxidonitrogen(1+) tetrafluoridoborate (nitrosonium tetrafluoridoborate), NO + BF 4 − , was refined on the basis of single-crystal X-ray diffraction data at 150 K. The compound crystallizes in the baryte structure type with orthorhombic  Pnma  symmetry. The crystal structure exhibits cationic disorder with equal occupation of N and O atoms at the same site.

Nitrosonium tetrafluoridoborate, NOBF4

Nitrosonium tetrafluoridoborate, NOBF₄