English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The title compound, [Mo 3 (C 31 H 46 NS 2 ) 3 S 7 ]I, crystallizes on a threefold rotational axis in  P 31 c  (space group No. 159). The [Mo 3 S 7 (S 2 CN(CH 2 C 6 H 3 -3,5- t Bu 2 ) 2 ) 3 ] +  cations are arrayed in sheets in the  ab  plane with interligand hydrophobic interactions between  tert -butyl groups guiding the packing arrangement. These cations form stacks parallel to the  c  axis with a separating distance of 10.9815 (6) Å (the  c  axis length) between the Mo 3  centroids. On the underside of the cluster, opposite the μ 3 -S 2−  ligand, the iodide counteranion forms close contacts of 3.166 (2) Å with the sulfur atoms of the μ 2 -S 2 2−  ligands. These contacts are less than the sum of the van der Waals radii of the atoms (1.8 and 2.1 Å for S and I, respectively), thus indicating an appreciable degree of covalency to the [Mo 3 S 7 (S 2 CN(CH 2 C 6 H 3 -3,5- t Bu 2 ) 2 ) 3 ] + ...I −  interactions.

iucrdata

Tris[N,N-bis(3,5-di-tert-butylbenzyl)dithiocarbamato-κ2 S,S′]-μ3-sulfido-tris-μ2-disulfido-triangulo-trimolybdenum(IV) iodide