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In the title complex, [Ni(C 7 H 3 NO 4 )(C 15 H 11 N 3 )]·C 3 H 7 NO·H 2 O, the Ni II  ion is six-coordinated within an octahedral geometry defined by three N atoms of the 2,2′:6′,2′′-terpyridine ligand, and two O atoms and the N atom of the pyridine-2,6-dicarboxylate di-anion. In the crystal, the complex molecules are stacked in columns parallel to the  a  axis being connected by π–π stacking [closest inter-centroid separation between pyridyl rings = 3.669 (3) Å]. The connections between columns and solvent molecules to sustain a three-dimensional architecture are of the type water-O—H...O(carbonyl) and pyridyl-, methyl-C—H...O(carbonyl).

iucrdata

(Pyridine-2,6-dicarboxylato-κ3 O,N,O′)(2,2′:6′,2′′- terpyridine-κ3 N,N′,N′′)nickel(II) dimethylformamide monosolvate monohydrate