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Single crystals of the title complex, [Zn(C 7 H 5 N 2 O 4 ) 2 (C 2 H 6 OS) 2 ] or [Zn(NBZH) 2 (DMSO) 2 ], were isolated from a dimethyl sulfoxide (DMSO) solution containing [Zn(NBZH) 2 ]·2H 2 O (NBZH = 3-nitrobenzohydroxamate anion). The asymmetric unit comprises of one  O , O ′-chelating NBZH anion, one O-bound DMSO ligand and one zinc(II) cation localized on an inversion centre. The three-dimensional crystal packing includes N—H...O and C—H...O hydrogen bonding, as well as O...H and H...H contacts identified by Hirshfeld isosurface analysis.

trans-Bis(dimethyl sulfoxide-κO)bis(3-nitrobenzohydroxamato-κ2 O,O′)zinc(II)

trans-Bis(dimethyl sulfoxide-κO)bis(3-nitrobenzohydroxamato-κ² O,O′)zinc(II)