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In the title compound, [Cd 2 (C 9 H 6 O 5 ) 2 (H 2 O) 2 ] n , the crystallographically distinct Cd II  cations are coordinated in pentagonal–bipyramidal and octahedral fashions. The 2-(carboxymethoxy)benzoate (cmb) ligands connect the Cd atoms into [Cd 2 (cmb) 2 (H 2 O) 2 )] n coordination polymer ribbons that are oriented along the  a- axis direction. Supramolecular layers are formed parallel to (01\overline{1}) by O—H...O hydrogen bonding between the ribbons. The supramolecular three-dimensional crystal structure of the title compound is then constructed by π–π stacking interactions with a centroid–centroid distance of 3.622 (2) Å between cmb ligands in adjacent layer motifs.

Poly[diaqua[μ4-2-(carboxylatomethoxy)benzoato][μ2-2-(carboxylatomethoxy)benzoato]dicadmium(II)]

Poly[diaqua[μ₄-2-(carboxylatomethoxy)benzoato][μ₂-2-(carboxylatomethoxy)benzoato]dicadmium(II)]