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The asymmetric unit of the title MOF, [Zn 5 (C 14 H 5 NO 10 S 2 ) 2 (OH) 2 (H 2 O) 10 ] n comprises three Zn II  atoms, one of which is located on a centre of inversion, a tetra-negative carboxylate ligand, one  μ 3 -hydroxide and five water molecules, each of which is coordinated. The Zn II  atom, lying on a centre of inversion, is coordinated by  trans  sulfoxide-O atoms and four water molecules in an octahedral geometry. Another Zn II  atom is coordinated by two carboxylate-O atoms, one hydroxy-O, one sulfoxide-O and a water-O atom to define a distorted trigonal–bipyramidal geometry; a close Zn...O(carboxylate) interaction derived from an asymmetrically coordinating ligand (Zn—O = 1.95 and 3.07 Å) suggests a 5 + 1 coordination geometry. The third Zn II  atom is coordinated in an octahedral fashion by two hydroxy-O atoms, one carboxylate-O, one sulfoxide-O and two water-O atoms, the latter being mutually  cis . In all, the carboxylate ligand binds six Zn II  ions leading to a three-dimensional architecture. In the crystal, all acidic donors form hydrogen bonds to oxygen acceptors to contribute to the stability of the three-dimensional architecture.

Polymeric poly[[decaaquabis(μ6-1,8-disulfonato-9H-carbazole-3,6-dicarboxylato)di-μ3-hydroxy-pentazinc] decahydrate]

Polymeric poly[[decaaquabis(μ₆-1,8-disulfonato-9H-carbazole-3,6-dicarboxylato)di-μ₃-hydroxy-pentazinc] decahydrate]