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The crystal structure of the centrosymmetic title compound, C 12 H 12 O 3 , confirms the relative stereochemistry. The 1,2-dihydrobenzene ring is in a flattened half-chair conformation. In the crystal, O—H...O hydrogen bonds link the molecules into layers lying parallel to (001).

1-[(1R*,2R*)-1,2-Dihydroxy-1,2-dihydronaphthalen-1-yl]ethan-1-one

1-[(1R,2R)-1,2-Dihydroxy-1,2-dihydronaphthalen-1-yl]ethan-1-one