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The title compound, [Co(C 6 H 6 NO 3 S) 2 (H 2 O) 2 ] n , was obtained from a mixture of Co(NO 3 ) 2 ·6H 2 O and a previously synthesized salt, namely CyNH 3 ·NH 2 PhSO 3 , in a 1:1 ratio (Cy = cyclohexyl; Ph = phenyl). The crystal structure consists of a three-dimensional supramolecular framework, in which polymeric layers are interconnected  via  N—H...O and O—H...O hydrogen bonding. The polymeric layers are formed by an interconnection of neighbouring cobalt(II) cations  via  NH 2 PhSO 3 −  bridges. Each cobalt(II) cation is surrounded by four NH 2 PhSO 3 −  moieties and two water molecules, leading to a distorted octahedral environment.

Poly[bis(μ-4-aminobenzenesulfonato-κ2 N:O)diaquacobalt(II)]

Poly[bis(μ-4-aminobenzenesulfonato-κ² N:O)diaquacobalt(II)]