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In the title hydrated salt, [CoCl(C 6 H 7 N)(C 2 H 8 N 2 ) 2 ]Cl 2 ·H 2 O, the Co III  ion exhibits a distorted octahedral coordination envirnoment defined by four N atoms of two ethane-1,2-diamine ligands, another N atom of the pyridine ligand and a Cl −  ligand. The pyridine N atom and the Cl −  ligand are in  cis  positions relative to each other. The crystal packing is dominated by intermolecular N—H...Cl, O—H...Cl and O—H...H hydrogen-bonding interactions involving the amino groups of the complex cation, the lattice water molecule and the non-coordinating Cl −  anions. Weak C—H...Cl interactions consolidate the three-dimensional hydrogen-bonded network structure.

Chloridobis(ethane-1,2-diamine-κ2 N,N′)(3-methylpyridine-κN)cobalt(III) dichloride monohydrate

Chloridobis(ethane-1,2-diamine-κ² N,N′)(3-methylpyridine-κN)cobalt(III) dichloride monohydrate