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The title compound, [Cd2(C8H8O4)2]n, crystallizes in the centrosymmetric monoclinic P21/n space group. Via cis-cyclo­hex-4-ene-1,2-di­carboxyl­ate ligands in two different binding modes, square pyramidally and penta­gonal bipyramidally coordinated Cd atoms are connected into coordination polymer layer motifs oriented parallel to the ab plane. These layered motifs are aggregated into the three-dimensional supra­molecular crystal structure of the title compound by means of crystal packing forces.

Poly[(μ5-cis-cyclohex-4-ene-1,2-dicarboxylato)(μ3-cis-cyclohex-4-ene-1,2-dicarboxylato)dicadmium(II)]

Poly[(μ₅-cis-cyclohex-4-ene-1,2-dicarboxylato)(μ₃-cis-cyclohex-4-ene-1,2-dicarboxylato)dicadmium(II)]