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The crystal structure of the title compound, [Ag 2 (VO 2 F 2 ) 2 (C 9 H 9 N 3 ) 4 ], is presented. The molecular complex is based on the heterobimetallic Ag I —V V  fragment {Ag I 2 (V V O 2 F 2 ) 2 ( tr ) 4 } supported by four 1,2,4-triazole ligands [4-benzyl-(4 H -1,2,4-triazol-4-yl)]. The triazole functional group demonstrates homo- and heterometallic connectivity (Ag—Ag and Ag—V) of the metal centers through the [–NN–] double and single bridges, respectively. The vanadium atom possesses a distorted trigonal–bipyramidal coordination environment [VO 2 F 2 N] with the Reedijk structural parameter τ = 0.59. In the crystal, C—H...O and C—H...F hydrogen bonds as well as C—H... π  contacts are observed involving the organic ligands and the vanadium oxofluoride anions. A Hirshfeld surface analysis of the hydrogen-bonding interactions is also described.

acta crystallographica. section e, crystallographic communications

Crystal structure of tetrakis(μ-4-benzyl-4H-1,2,4-triazole-κ2 N 1:N 2)tetrafluoridodi-μ2-oxido-dioxidodisilver(I)divanadium(V)