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The title compound, [Eu(C 9 H 10 BN 6 )(C 19 H 15 O 2 ) 2 (C 3 H 7 NO)] or [TpEu(Anthracac) 2 (DMF)], was synthesized by reaction of a tris(pyrazolyl)borate (Tp − ) Eu 3+  complex with 3-(anthracen-9-yl)pentane-2,4-dione (HAnthracac) in the presence of triethylamine. In the title compound, Eu 3+  is located in an octavertex square-pyramidal coordination environment. In the two Anthracac −  ligands, the anthracene and nearly planar acetylacetonate fragments are almost orthogonal. Neighboring molecules of TpEu(Anthracac) 2 (DMF) are connected in the crystal by intermolecular van der Waals interactions, while π-stacking interactions are limited to the edges of two anthracene rings.

acta crystallographica. section e, crystallographic communications

Bis[3-(anthracen-9-yl)pentane-2,4-dionato-κ2 O,O′](N,N-dimethylformamide-κO)[tris(pyrazol-1-yl-κN 2)hydroborato]europium(III)