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Tin(IV) trioxidotellurate(IV), SnTe 3 O 8 , is a member of the isotypic  M IV Te IV 3 O 8  ( M  = Ti, Zr, Hf, Sn) series crystallizing with eight formula units per unit cell in space group  Ia \overline{3}. In comparison with the previous crystal structure model of SnTe 3 O 8  based on powder X-ray diffraction data [Meunier &amp; Galy (1971).  Acta Cryst.  B 27 , 602–608], the current model based on single-crystal X-ray data is improved in terms of precision and accuracy. Nearly regular [SnO 6 ] octahedra (Sn site symmetry .\overline{3}.) are situated in the voids of an oxidotellurate(IV) framework built up by corner-sharing [TeO 4 ] bisphenoids (Te site symmetry 2..). A quantitative structural comparison revealed a very high degree of similarity for the structures with  M  = Ti, Zr, Sn in the  M IV Te 3 O 8  series.

Single crystals of SnTe3O8 in the millimetre range grown by chemical vapor transport reactions

Single crystals of SnTe₃O₈ in the millimetre range grown by chemical vapor transport reactions