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The title compound, [Cu 2 (C 19 H 23 N 7 O)(C 2 H 3 O 2 ) 4 ]  n  , was obtained via reaction of copper(II) acetate with the coordinating ligand, 6-eth-oxy- N  2 , N  4 -bis-[2-(pyridin-2-yl)eth-yl]-1,3,5-triazine-2,4-di-amine. The crystallized product adopts the monoclinic P 2 1 / c space group. The metal core exhibits a paddle-wheel structure typical for dicopper tetra-acetate units, with triazine and pyridyl nitro-gen atoms from different ligands coordinating to the two axial positions of the paddle wheel in an asymmetric manner. This forms a coordination polymer with the segments of the polymer created by the c -glide of the P 2 1 / c setting of the space group. The resulting chains running along the c -axis direction are held together by intra-molecular N-H⋯O hydrogen bonding. These chains are further packed by dispersion forces, producing an extended three-dimensional structure.

acta crystallographica. section e, crystallographic communications

Synthesis and crystal structure of catena-poly[[tetra-μ-acetato-copper(II)]-μ-6-ethoxy-N 2,N 4-bis[2-(pyridin-2-yl)ethyl]-1,3,5-triazine-2,4-diamine]