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In the hydrated title salt, [C 22 H 48 N 4 ]Cl 4 ·4H 2 O, the cation lies about an inversion centre. The macrocyclic ring adopts an exodentate (3,4,3,4)- D  conformation. In the crystal, O—H⋯Cl, N—H⋯Cl and N—H⋯O hydrogen bonds connect the chloride anions, tetra­protonated cations and water mol­ecules into a three-dimensional network.

acta crystallographica. section e, crystallographic communications

Crystal structure of 3,14-diethyl-2,6,13,17-tetraazoniatricyclo[16.4.0.0<sup>7,12</sup>]docosane tetrachloride tetrahydrate from synchrotron X-ray data

Crystal structure of 3,14-diethyl-2,6,13,17-tetraazoniatricyclo[16.4.0.07,12]docosane tetrachloride tetrahydrate from synchrotron X-ray data

Crystal structure of 3,14-diethyl-2,6,13,17-tetraazoniatricyclo[16.4.0.0^7,12]docosane tetrachloride tetrahydrate from synchrotron X-ray data