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The mononuclear title complex, [Eu(C 24 H 34 O 4 P) 3 (CH 4 O) 5 ]·CH 4 O, ( 1 ), has been obtained as a minor product in the reaction between EuCl 3 (H 2 O) 6 and lithium bis-(2,6-diiso-propyl-phen-yl) phosphate in a 1:3 molar ratio in a methanol medium. Its structure exhibits monoclinic ( P 2 1 / c ) symmetry at 120 K and is isostructural with the La, Ce and Nd analogs reported previously [Minyaev et al. (2018 a ▸). Acta Cryst. C 74 , 590-598]. In ( 1 ), all three bis-(2,6-diiso-propyl-phen-yl) phosphate ligands display the terminal κ 1  O -coordination mode. All of the hy-droxy H atoms are involved in O-H⋯O hydrogen bonding, exhibiting four intra-molecular and two inter-molecular hydrogen bonds. Photophysical studies have demonstrated luminescence of ( 1 ) with a low quantum yield.

Crystal structure of tris[bis(2,6-diisopropylphenyl) phosphato-κO]pentakis(methanol-κO)europium methanol monosolvate