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The reaction cavity of the nitro group in the crystal of the title compound, [CoCl(NO 2 )(C 10 H 24 N 4 )]Cl, (I), was investigated to confirm that it offers sufficient free space for linkage isomerization to occur in accordance with the observed photochemical reactivity. The complex cation has crystallographic 2/ m symmetry and the nitro and chloro ligands at the trans positions are statistically disordered. The complete cyclam ligand is generated by symmetry from a quarter of the mol-ecule. In the crystal of (I), the complex cations and Cl - ions are linked into a three-dimensional network by N-H⋯Cl(counter-ion) hydrogen bonds.

acta crystallographica. section e, crystallographic communications

Investigation of nitro–nitrito photoisomerization: crystal structure oftrans-chloridonitro(1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)cobalt(III) chloride