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The asymmetric unit of the title compound {systematic name: 3-[( tert -butyl-diphenyl-sil-yl)-oxy]propane-1,2-diol, C 19 H 26 O 3 Si}, contains eight chiral mol-ecules ( Z ' = 8). These mol-ecules are connected via a complex system of hydrogen bonds into an infinite assembly along the [100] axis; hydro-phobic tert -butyl and phenyl groups form an external coating of the assembly. These assemblies are packed by weak inter-molecular inter-actions in a peculiar formation resembling a 'header bond' masonry brick wall. Disorder of flexible fragments increases with temperature but the same crystal structure exists from 120 to 220 K (and most probably to the melting point at 334 K).

Crystal structure of (S)-1-O-tert-butyldiphenylsilylglycerol: eight chiral molecules in a triclinic cell