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In the title mol­ecular salt, C 14 H 22 NO + ·Cl − , the pyrrolidinium ring adopts a twisted conformation about one of the N—C bonds. It is oriented at a dihedral angle of 42.0 (1)° with respect to the benzene ring. The torsion angle for the central N—C—C—C ar  (ar = aromatic) linkage is 163.74 (15)°. In the crystal, the components are linked  via  N—H⋯Cl and O—H⋯Cl hydrogen bonds, forming zigzig chains along the  b -axis direction. These chains are connected along the  c  axis by very weak C—H⋯π inter­actions, forming a two-dimensional supra­molecular network.

Crystal structure of [(2S,3R)-3-hydroxy-3-phenylbutan-2-yl]pyrrolidinium chloride