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The title compound, C 5 H 9 BrN 4 O, was obtained as a minor by-product in the synthesis of 4-di­methyl­amino-1-methyl-1,2,4-triazolin-5-one. Except for the methyl groups of the 4-dimethylamino moiety, all the non-H atoms lie on a crystallographic mirror plane." In the crystal, the mol­ecules are linked by C—Br⋯O=C inter­actions [Br⋯O = 2.877 (2) Å, C—Br⋯O = 174.6 (1)°] into infinite chains in the  c- axis direction.

Crystal structure of 3-bromo-4-dimethylamino-1-methyl-1,2,4-triazol-5(4H)-one