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Preliminary observations of the interplay of radiation damage with spin crossover
Author(s) -
Chernyshov Dmitry,
Dyadkin Vadim,
Törnroos Karl Wilhelm
Publication year - 2022
Publication title -
acta crystallographica section b
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.604
H-Index - 33
ISSN - 2052-5206
DOI - 10.1107/s205252062200467x
Subject(s) - synchrotron radiation , spin crossover , crossover , radiation , spin (aerodynamics) , diffraction , spin states , synchrotron , physics , materials science , condensed matter physics , optics , computer science , thermodynamics , artificial intelligence
Intense synchrotron radiation makes time‐resolved structural experiments with increasingly finer time sampling possible. On the other hand, radiation heating, radiation‐induced volume change and structural disorder become more frequent. Temperature, volume change and disorder are known to be coupled with equilibrium in molecular spin complexes, balancing between two or more spin state configurations. Combining single‐crystal diffraction and synchrotron radiation it is illustrated how the radiation damage and associated effects can affect the spin crossover process and may serve as yet another tool to further manipulate the spin crossover properties.