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The title compound, [Mn(C 6 H 4 N 5 ) 2 (H 2 O) 4 ]·4H 2 O, was obtained by the solution reaction of MnCl 2  and 3-(2 H -tetra­zol-5-yl)pyridine. The Mn II  atom, located on an inversion center, shows a slightly distorted octa­hedral geometry and is coordinated by two pyridine N atoms from two 5-(pyridin-3-yl)tetra­zolide ligands occupying  trans  positions and four water mol­ecules. In the crystal, the mononuclear complex mol­ecules and solvent water mol­ecules are connected into a three-dimensional framework by O—H⋯N and O—H⋯O hydrogen bonds.

Tetraaquabis[5-(pyridin-3-yl)tetrazolido-κN5]manganese(II) tetrahydrate

Tetraaquabis[5-(pyridin-3-yl)tetrazolido-κN⁵]manganese(II) tetrahydrate