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The title compound, C 9 H 12 ClN 4+ ·Cl − , is a natural metabolic product of imidacloprid [systematic name: ( E )-1-(6-chloro-3-pyridyl­meth­yl)- N -nitro­imidazolidin-2-yl­idene­amine] and was obtained by the reduction of the latter using Fe in HCl. The dihedral angle between the pyridine and imidazole rings is 62.09 (12)°. The crystal structure is stabilized by N—H⋯Cl and C—H⋯Cl inter­actions involving the chloride anion. The pyridine N and the chloride atoms are not involved in inter­molecular inter­actions.

1-[(6-Chloropyridin-3-yl)methyl]imidazolidin-2-iminium chloride