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The dinuclear title compound, [Fe 2 (C 2 H 4 S 2 )(C 24 H 20 OP 2 )(CO) 5 ] or (μ-SCH 2 CH 2 S-μ)Fe 2 (CO) 5 [Ph 2 PP(O)Ph 2 ], con­tains a butterfly-shaped Fe 2 S 2  core in which the Fe⋯Fe separation is 2.5275 (6) Å. One of the Fe atoms is also coordinated to three carbonyl ligands and the other to two carbonyl ligands and one phosphane ligand [Ph 2 PP(O)Ph 2 ]. Both Fe-atom geometries could be described as grossly distorted octa­hedral and the Ph 2 PP(O)Ph 2  ligand lies  trans  to the Fe⋯Fe link.

acta crystallographica. section e

Pentacarbonyl-1κ2C,2κ3C-[(diphenylphosphoryl)diphenylphosphane-1κP]-μ-ethane-1,2-dithiolato-1:2κ4S,S′:S,S′-diiron(I)(Fe—Fe)