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In the title compound, C 22 H 29 Cl 3 O 13 , the glucopyran ring exists in the chair conformation while the glucofuran ring adopts an envelope conformation. Intra­molecular C—H⋯O hydrogen bonds occur. In the crystal, adjacent mol­ecules are linked by weak inter­molecular C—H⋯O hydrogen bonds.

2,3,6,3′,4′-Penta-O-acetyl-4,1′,6′-trichloro-4,1′,6′-trideoxysucrose