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The complex mol-ecule of the title compound, [Cu(3)Br(C(22)H(28)N(4)O(2))(2)]Br·2C(3)H(7)NO, contains three copper atoms, two of which are five-coordinate within a square-pyramidal environment and linked by a bridging Br atom occupying the apical position in each square pyramid. The remaining Cu atom is four-coordinate but with considerable tetra-hedral disortion [the dihedral angle between the two chelate planes is 69.21 (7)°]. There are two mol-ecules of dimethyl-formamide (DMF) present as solvent mol-ecules, one of which is disordered over two equivalent conformations with occupancies of 0.603 (5) and 0.397 (5). The amine H atoms are involved in both inter- and intra-molecular hydrogen-bonding inter-actions with the Br and O atoms of the cation, as well as with the O atom of the ordered DMF mol-ecule.

μ-Bromido-bis{μ-2,2′-[4,7-diazadecane-1,10-diylbis(nitrilomethanylylidene)]diphenolato}tricopper(II) bromide dimethylformamide disolvate